Identifikasi Komponen Kimia Damar Mata Kucing (Shorea Javanica) dengan Metode Pirolisis-GC/MS
Abstract
The aim of this research was to identify chemical compounds in cat eye dammar. The method included functional groups characterizationby infrared spectrophotometer and identification using Pyrolisis-GC/MS. Infrared spectra of crude sample showed that there were somefunctional groups such as alkyl, carbonyl, vinyl, and hydroxyl. Identification by Pyrolisis-GC/MS showed that dammar consisted of at least67 compounds. This natural gum components could be categorized into 4 groups, i.e. tetra cyclic hydrocarbon (30 compounds, 49.57%),penta cyclic (3 compounds, 2.56%), C 15 compounds (11 compounds, 17.09%), and other group (23 compounds, 18.26%). According to thePy-GC/MS data, brassicasterol is the highest relative concentration in dammar, i.e. 20%.
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Aarssen, B.G.K., van de Leeuw, J.W., Collinson, M., Boon, J.J & Goth, K. 1994. Occurrence of polycadinene in fossil and recent resins. Geochimica et Cosmochimica Acta 58(1): 223- 229.
Anderson, K.B & Muntean, J.V. 2000. The nature and fate of natural resins in the geosphere. Part X. Structural characteristics of the macromolecular constituents of modern Dammar resin and Class II ambers. Geochemical Transactions 1: 1-9.
Doelen, V.D., Berg, V.D & Boon, J.J. 1998. Comparative chromatographic and mass spectrometric studies of triterpenoid varnishes fresh material and aged samples from paintings. Studies in Conservation 43(4): 249-264.
Edriana, E., Dahlian, E & Sumadiwangsa, E.S. 2004. Teknik pembuatan pernis dari damar untuk usaha kecil. Jurnal Penelitian Hasil Hutan 22(4): 205-213.
Lakerveld & A van 2007. Price Determination and Upgrading Within the Damar Trade Chain. Tesis Pasca Sarjana. Amsterdam: International Development Studies.
Mills, J.S & Werner, A.E.A 1955. The chemistry of dammar resin. Journal of Chemistry Society: 3132-3140. Diacu dalam Doelen et al. 1998. Comparative chromatographic and mass spectrometric studies of triterpenoid varnishes fresh material and aged samples from paintings. Studies in Conservation 43(4): 249-264.
Nakamoto, K. 1997. Infrared and Raman Spectra of Inorganic and Coordination Compunds. Part A: Theory and Applications in Inorganic Chemistry. Ed ke-5. New York: J Wiley.
Sahelian, R. 2009. Health benefit of brassicasterol. Free Supplement Res Update Newsletter. http://www.raysahelian.com (5 Feb 2009).
Sari, R.K. 2002. Isolasi dan identifikasi komponen bioaktif dari damar mata kucing (Shorea javanica K.et.V). Disertasi Pascasarjana. Bogor: IPB.
Scalarone, D., van der Horst, J., Boon, J.J & Chiantore, O. 2003. Direct-temperature mass spectrometric detection of volatile terpenoids and natural terpenoid polymersin fresh and artificially aged resins. Journal of Mass Spectrometry 38(6): 607-617.
Shimadzu. 2008. GCMS-QP2010 Plus. http://www.shimadzu.com [16 Sep 2008].
Sumadiwangsa, E.S & Gusmailina. 2006. Teknologi Budidaya, Pemanfaatan dan Pengembangan Hasil Hutan Bukan Kayu. Bogor: Dephut
DOI: http://dx.doi.org/10.31258/jnat.14.1.155-159
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