Kitosan dari Limbah Kulit Kepiting Rajungan (Portunus sanginolentus L.) sebagai Adsorben Zat Warna Biru Metilena

Matheis F.J.D.P. Tanasale, Amos Killay, Marsela S Laratmase

Abstract


The chitosan from shell of crabs (Portunus sanginolentus L.) waste was produced from deproteinization, demineralization, depigmentation,and deacetylation steps. This process was obtained 22.66% chitosan which identified by FTIR spectrophotometry and had 65.47% degree ofdeacetylation. This chitosan was used to adsorb methylene blue dye which fit to the Langmuir isotherm with 0.0312 l mg -1 equilibriumconstant of adsorption (K) and 4.20 mg g -1 maximum capacity of adsorption (q m).

Keywords


adsorpsi, biru metilena, isoterm Langmuir, kitosan

Full Text:

PDF

References


Adamson, A.W. 1990. Physical Chemistry of Surfaces, 5th Edition. New York: A Wiley-Interscience Publ.

Alzaydien, A.S. 2009. Adsorption of methylene blue from aqueous solution onto a low-cost natural Jordanian tripoli. Am J Environ Sci 5(3): 197-208.

Annadurai, G., Sheeja, R.Y., Balan, M,S., Murugesan, T & Srinivasamoorthy, V.R. 1999. Factorial design of experiments in the determination of adsorpstion equilibrium constants for basic methylene blue using biopolymer. Bioprocess & Biosystems Eng 20: 37-43.

Austin, P.R., Brine, C.J1., Castle, J.E & Zikakis, J.P. 1981. Chitin: new facets of research. Science 212: 749-753.

Bhattacharya, K.G & Sharma, A. 2005. Kinetics and thermodynamics of methylene blue adsorption on neem (Azadirachta indica) leaf powder. Dyes Pigm 65: 51-59.

Cahyaningrum, S.E & Amaria. 2005. Utilization of Penaus monodon shrimp shell waste as adsorbent of cadmium (II) in water medium. Indo J Chem 5: 130-134.

Cengiz, S & Cavaz, L. 2008. Removal of methylene blue by invasive marine seaweed: Caulerpa racemosa var. Cylindracea. Bioresour. Technol 99: 2357-2363.

Crini, G. 2006. Non-conventional low-cost adsorbents for dye removal: a review. Bioresour. Technol 97: 1061-1085.

Crini, G & Badot, P.-M. 2008. Application of chitosan, a natural aminopolysaccharide, for removal from aqueous solution by adsorption processes using batch studies: a review of recent literature. Prog Polym Sci 33: 399-447.

Crini, G., Martel, B & Torri, G. 2008. Adsorption of C.I. basic blue 9 on chitosan-based materials. Int. J Environ Pollut 34: 451-465.

Darjito & Purwonugroho, D & Nisa, S.N. 2006. Study on adsorpstion of Cd(II) by chitosan-alumina. Indo J Chem 6: 238-244.

Dinas Perikanan & Kelautan Propinsi Maluku. 2007. Buku Tahunan Statistika Perikanan Propinsi Maluku Tahun 2007. Ambon: Dinas Perikanan dan Kelautan Propinsi Maluku.

Figueiredo, S.A., Boaventure, R.A & Loureiro, J.M. 2000. Color removal with natural adsorbents: Modeling, simulation and experimental. Separation & Purification Techno 20: 129-141.

Fransina, E.G & Tanasale, M.F.J.D.P. 2007. Studi kinetika adsorpsi biru metilena pada kitin dan kitosan. J Sains MIPA 13: 171-176.

Gürses, A., Karaca, S. Dogar, C., Bayrak, R., Acikyildiz, M & Yalcin, M. 2004. Determination of adsorptive properties of clay/water system: methylene blue sorption. J Colloid Int Sci 269: 310-314.

Handayani, N. 2003. Adsorpsi zat warna tartrazine pada khitosan. Skripsi Sarjana. Jurusan Kimia FMIPA Universitas Hasanuddin.

Kannan, N & Sundaram, M. 2001. Kinetics and mechanism of removal of methylene blue by adsorption on various carbonsda comparative study. Dyes Pigm 51: 25-40.

Khan, T.A., Peh, K.K & Ching, H.S. 2002. Reporting degree of deacetylation values of chitosan: the influence of analytical methods. J Pharm Pharmceut Sci 5: 205-212.

Kim, S.B & Lee, J.H. 2002. Removal of anionic dyes by acid- treated chitin. Hwahak Konghak 40(5): 635-639.

Longhinotti, E., Pozza, F. Furlan, L., de Sanchez, M.N.M., Klug, M., Laranjeira, M.C.M & Favere, V.T. 1998. Adsorption of anionic dyes on the biopolymer chitin. J Braz Chem Soc 9: 435-440.

Lynam, M.M., Kilduff, J.E & Weber, W.J.Jr. 1995. Adsorption of p-nitrophenol from dilute aqueous solution. J Chem Educ 72: 80-84.

Mathur, N.K & Narang, C.K. 1990. Chitin and chitosan: versatile polysaccharides from marine animals. J Chem Educ 67: 938- 942.

Monvisade, P & Siriphannon, P. 2009. Chitosan intercalated montmorillonite: preparation, characterization and cationic dye adsorption. Appl Clay Sci 42: 427-431.

No, H.K., Meyers, S.P & Lee, K.S. 1989. Isolation and characterization of chitin from crawfish shell waste. J Agric Food Chem 37: 575-579.

No, H.K & Meyers, S.P. 1997. Preparation of chitin and chitosan, dalam R.A.A. Muzzarelli dan M.G. Peter, Chitin Handbook, European Chitin Society, 475-489.

Potgieter, J.H. 1991. Adsorption of methylene blue on activated carbon: an experiment illustrating both the Langmuir and Freundlich isotherms. J Chem Educ 68: 349-350.

Purwantiningsih. 1993. Isolasi kitin dan senyawaan kimia dari limbah udang windu (Penaeus monodon). Buletin Kimia 8: 1- 13.

Rahman, I.A & Saad, B. 2003. Utilization of guava seeds as a source of activated carbon for removal of methylene blue from aqueous solution. Malaysian J Chem 5: 8-14.

Santosa, S.J., Narsito & Lesbani, A. 2006. Sorption-desorption mechanism of Zn (II) and Cd (II) on chitin. Indo J Chem 6: 47-51.

Sastrohamidjojo, H. 1992. Spektroskopi Inframerah. Yogyakarta: Liberty.

Sugita, P., Wukirsari, T., Sjahriza, A & Wahyono, D. 2009. Kitosan: Sumber Biomaterial Masa Depan. Bogor: Penerbit IPB Press.

Tanasale, M.F.J.D.P., Killay, A & Saily, M. 2006. Kitosan dari limbah udang windu (Penaeus monodon) sebagai adsorben fenol. J Alchemy 5: 23–30.

Wang, L., Zhang, J & Wang, A. 2008. Removal of methylene blue from aqueous solution using chitosan-g-poly(acrylic acid)/ montmorillonite superadsorbent nanocomposite. Colloid Surfaces A 322: 47-53.

Weng, C.H & Pan, Y.F. 2006. Adsorption characteristics of methylene blue from aqueous solution by sludge ash. Colloid Surfaces A 274: 154-162

Williams, D.H & Fleming, I. 1998. Spectroscopic Methods in Organic Chemistry, 5th Edition. London: McGraw-Hill.

Zheng, S., Yang, Z., Jo, D.H & Park, Y.H. 2004. Removal of chlorophenols from groundwater by chitosan sorption. Water Res 38: 2314-2321.




DOI: http://dx.doi.org/10.31258/jnat.14.1.165-171

Refbacks

  • There are currently no refbacks.


Copyright (c) 2012 Matheis F.J.D.P. Tanasale, Amos Killay, Marsela S Laratmase

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.